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Rate Constants (ki(105 M1 s1) for Substitution Reactions of Various PtII-Nucle- obase Complexes with Different Nucleophiles (Y) in Aqueous Solutiona) Complex Yb) cis-[Pt(NH3)2(G-N(7))2]2 tu tu CN cis-[Pt(NH3)2(G-N(7))(A-N(7))]2 tu cis-[Pt(NH3)2(G-N(7))(A-N(1))]2 tu [Pt(dien)(G-N(7))]2 tu tu I H2O [Pt(dien)(A-N(7))]2 tu tu I H2O cis-[Pt(NH3)2(1-MeU)(H2O)] tu I cis-[Pt(NH3)2(1-MeU)2] I H2O cis-[Pt(NH3)2(5-GMP-N(7))2] tu trans-[Pt(NH3)2(5-GMP-N(7))2] tu kY1 5.
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